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      Evaluation of the Impact of Different Natural Zeolite Treatments on the Capacity of Eliminating/Reducing Odors and Toxic Compounds

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          Abstract

          Unlike odorants that mask odors, natural zeolite acts as a molecular sieve that captures and eliminates odors. Different treatment methods can be applied to influence the properties of the natural zeolites. To enhance the odor adsorption capacities of the natural zeolite two types of treatment methods were applied: chemical (acid, basic) and thermal. The initial natural zeolites and the activated one were characterized using X-ray diffraction (XRD) and scanning electron microscope (SEM-EDX). Two experiments were performed to establish the odor adsorption capacity of the activated natural zeolites. The best zeolite for the adsorption of humidity, ammonia and hydrogen sulfide was the 1–3 mm zeolite activated through thermal treatment. For the adsorption of PAHs, the best zeolite was the one activated through basic treatment, with an adsorption capacity of 89.6 ng/g.

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          Most cited references35

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          Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)

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            Advances in theory and their application within the field of zeolite chemistry.

            Zeolites are versatile and fascinating materials which are vital for a wide range of industries, due to their unique structural and chemical properties, which are the basis of applications in gas separation, ion exchange and catalysis. Given their economic impact, there is a powerful incentive for smart design of new materials with enhanced functionalities to obtain the best material for a given application. Over the last decades, theoretical modeling has matured to a level that model guided design has become within reach. Major hurdles have been overcome to reach this point and almost all contemporary methods in computational materials chemistry are actively used in the field of modeling zeolite chemistry and applications. Integration of complementary modeling approaches is necessary to obtain reliable predictions and rationalizations from theory. A close synergy between experimentalists and theoreticians has led to a deep understanding of the complexity of the system at hand, but also allowed the identification of shortcomings in current theoretical approaches. Inspired by the importance of zeolite characterization which can now be performed at the single atom and single molecule level from experiment, computational spectroscopy has grown in importance in the last decade. In this review most of the currently available modeling tools are introduced and illustrated on the most challenging problems in zeolite science. Directions for future model developments will be given.
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              Categorical Dimensions of Human Odor Descriptor Space Revealed by Non-Negative Matrix Factorization

              In contrast to most other sensory modalities, the basic perceptual dimensions of olfaction remain unclear. Here, we use non-negative matrix factorization (NMF) – a dimensionality reduction technique – to uncover structure in a panel of odor profiles, with each odor defined as a point in multi-dimensional descriptor space. The properties of NMF are favorable for the analysis of such lexical and perceptual data, and lead to a high-dimensional account of odor space. We further provide evidence that odor dimensions apply categorically. That is, odor space is not occupied homogenously, but rather in a discrete and intrinsically clustered manner. We discuss the potential implications of these results for the neural coding of odors, as well as for developing classifiers on larger datasets that may be useful for predicting perceptual qualities from chemical structures.
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                02 July 2021
                July 2021
                : 14
                : 13
                : 3724
                Affiliations
                [1 ]INCDO-INOE2000, Research Institute for Analytical Instrumentation, 67 Donath Str., 400293 Cluj-Napoca, Romania; vanda.fuss@ 123456icia.ro (V.L.B.F.); lucian.dordai@ 123456icia.ro (L.D.); marius.roman@ 123456icia.ro (M.R.); oana.cadar@ 123456icia.ro (O.C.)
                [2 ]Enviro Naturals Agro LtD., 12A Preciziei Str., 062203 Bucharest, Romania; gabriel@ 123456enviro-naturals.com
                Author notes
                [* ]Correspondence: anca.naghiu@ 123456icia.ro
                Author information
                https://orcid.org/0000-0002-0879-9211
                https://orcid.org/0000-0003-1418-689X
                Article
                materials-14-03724
                10.3390/ma14133724
                8269797
                34279291
                bc9844b3-0f9c-4799-a515-cd54e554342b
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 27 May 2021
                : 30 June 2021
                Categories
                Article

                natural zeolite,thermal treatment,chemical treatment,odor,polycyclic aromatic hydrocarbons

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