The Effectiveness of Pahae Natural Zeolite–Cocoa Shell Activated Charcoal Nanofilter as a Water Adsorber in Bioethanol Purification

Abstract

Pahae natural zeolite potentially can be used as a filtration material because of its high adsorption capacity. However, it is known that other supportive materials such as activated charcoal are needed to optimize the utilization of natural zeolite as an adsorber. This study aims to investigate the potential use of activated charcoal which was synthesized from cocoa shells waste and natural zeolite in nanosize as the adsorber in order to increase the concentration of bioethanol. The mixing process of nanozeolite and activated charcoal of cocoa shells was carried out through mechanical mixing, while the nanofilter was made using a press-printing technique followed by sintering at several temperature variations. The results showed that the activated zeolite produced in this study has a particle size of 118.4 nm with water absorption capacity of 52.08%. In line with that, the bioethanol concentration was increased up to 78.92% during the adsorption with a 45 min contact time with water vapor. Thus, based on the results, it can be concluded that nanosized zeolite-based adsorbents and activated charcoal produced from cocoa shells can be utilized as adsorbers to significantly increase the concentration of bioethanol generated.