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      Dynamic plasmonic colour display

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      1 , 2 , 1 , a , 1 , 2
      Nature Communications
      Nature Publishing Group

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          Abstract

          Plasmonic colour printing based on engineered metasurfaces has revolutionized colour display science due to its unprecedented subwavelength resolution and high-density optical data storage. However, advanced plasmonic displays with novel functionalities including dynamic multicolour printing, animations, and highly secure encryption have remained in their infancy. Here we demonstrate a dynamic plasmonic colour display technique that enables all the aforementioned functionalities using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent magnesium nanoparticles, which serve as dynamic pixels, allow for plasmonic colour printing, tuning, erasing and restoration of colour. Different dynamic pixels feature distinct colour transformation kinetics, enabling plasmonic animations. Through smart material processing, information encoded on selected pixels, which are indiscernible to both optical and scanning electron microscopies, can only be read out using hydrogen as a decoding key, suggesting a new generation of information encryption and anti-counterfeiting applications.

          Abstract

          Here Duan et al. demonstrate dynamic plasmonic colour displays using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent nanoparticles, which serve as dynamic pixels, allow plasmonic colour printing, tuning, erasing, restoration of colour and encoding of information.

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          Nano-optics from sensing to waveguiding

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            Printing colour at the optical diffraction limit.

            The highest possible resolution for printed colour images is determined by the diffraction limit of visible light. To achieve this limit, individual colour elements (or pixels) with a pitch of 250 nm are required, translating into printed images at a resolution of ∼100,000 dots per inch (d.p.i.). However, methods for dispensing multiple colourants or fabricating structural colour through plasmonic structures have insufficient resolution and limited scalability. Here, we present a non-colourant method that achieves bright-field colour prints with resolutions up to the optical diffraction limit. Colour information is encoded in the dimensional parameters of metal nanostructures, so that tuning their plasmon resonance determines the colours of the individual pixels. Our colour-mapping strategy produces images with both sharp colour changes and fine tonal variations, is amenable to large-volume colour printing via nanoimprint lithography, and could be useful in making microimages for security, steganography, nanoscale optical filters and high-density spectrally encoded optical data storage.
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              Optical properties of intrinsic silicon at 300 K

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                Author and article information

                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group
                2041-1723
                24 February 2017
                2017
                : 8
                : 14606
                Affiliations
                [1 ]Max Planck Institute for Intelligent Systems , Heisenbergstrasse 3, 70569 Stuttgart, Germany
                [2 ]Kirchhoff Institute for Physics, University of Heidelberg , Im Neuenheimer Feld 227, 69120 Heidelberg, Germany
                Author notes
                Article
                ncomms14606
                10.1038/ncomms14606
                5333121
                28232722
                11312535-d37f-415a-b310-f9e28f390bc4
                Copyright © 2017, The Author(s)

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 23 June 2016
                : 12 January 2017
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