The structural nature of high-density amorphous ice (HDA), which forms through low-temperature pressure-induced amorphization of the 'ordinary' ice I, is heavily debated. Clarifying this question is not only important for understanding the complex condensed states of H\(_2\)O but also in the wider context of pressure-induced amorphization processes, which are encountered across the entire materials spectrum. We first show that ammonium fluoride (NH\(_4\)F), which has a similar hydrogen-bonded network to ice I, also undergoes a pressure collapse upon compression at 77 K. However, the product material is not amorphous but NH\(_4\)F II, a high-pressure phase isostructural with ice IV. This collapse can be rationalized in terms of a highly effective mechanism. In the case of ice I, the orientational disorder of the water molecules leads to a deviation from this mechanism and we therefore classify HDA as a 'derailed' state along the ice I to ice IV pathway.