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      Liquid crystal-powered Mie resonators for electrically tunable photorealistic color gradients and dark blacks

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          Abstract

          Taking inspiration from beautiful colors in nature, structural colors produced from nanostructured metasurfaces have shown great promise as a platform for bright, highly saturated, and high-resolution colors. Both plasmonic and dielectric materials have been employed to produce static colors that fulfil the required criteria for high-performance color printing, however, for practical applications in dynamic situations, a form of tunability is desirable. Combinations of the additive color palette of red, green, and blue enable the expression of further colors beyond the three primary colors, while the simultaneous intensity modulation allows access to the full color gamut. Here, we demonstrate an electrically tunable metasurface that can represent saturated red, green, and blue pixels that can be dynamically and continuously controlled between on and off states using liquid crystals. We use this to experimentally realize ultrahigh-resolution color printing, active multicolor cryptographic applications, and tunable pixels toward high-performance full-color reflective displays.

          Abstract

          Ellipsoidal-shaped Mie resonators are integrated with a liquid crystal cell to demonstrate electrically tunable reflective structural color metasurfaces that can be modulated continuously from bright spectral colors to dark blacks.

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          Light propagation with phase discontinuities: generalized laws of reflection and refraction.

          Conventional optical components rely on gradual phase shifts accumulated during light propagation to shape light beams. New degrees of freedom are attained by introducing abrupt phase changes over the scale of the wavelength. A two-dimensional array of optical resonators with spatially varying phase response and subwavelength separation can imprint such phase discontinuities on propagating light as it traverses the interface between two media. Anomalous reflection and refraction phenomena are observed in this regime in optically thin arrays of metallic antennas on silicon with a linear phase variation along the interface, which are in excellent agreement with generalized laws derived from Fermat's principle. Phase discontinuities provide great flexibility in the design of light beams, as illustrated by the generation of optical vortices through use of planar designer metallic interfaces.
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            Imaging-based molecular barcoding with pixelated dielectric metasurfaces

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              Dynamic plasmonic colour display

              Plasmonic colour printing based on engineered metasurfaces has revolutionized colour display science due to its unprecedented subwavelength resolution and high-density optical data storage. However, advanced plasmonic displays with novel functionalities including dynamic multicolour printing, animations, and highly secure encryption have remained in their infancy. Here we demonstrate a dynamic plasmonic colour display technique that enables all the aforementioned functionalities using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent magnesium nanoparticles, which serve as dynamic pixels, allow for plasmonic colour printing, tuning, erasing and restoration of colour. Different dynamic pixels feature distinct colour transformation kinetics, enabling plasmonic animations. Through smart material processing, information encoded on selected pixels, which are indiscernible to both optical and scanning electron microscopies, can only be read out using hydrogen as a decoding key, suggesting a new generation of information encryption and anti-counterfeiting applications.
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                Author and article information

                Contributors
                ykkim@postech.ac.kr
                jsrho@postech.ac.kr
                Journal
                Light Sci Appl
                Light Sci Appl
                Light, Science & Applications
                Nature Publishing Group UK (London )
                2095-5545
                2047-7538
                29 April 2022
                29 April 2022
                2022
                : 11
                : 118
                Affiliations
                [1 ]GRID grid.49100.3c, ISNI 0000 0001 0742 4007, Department of Mechanical Engineering, , Pohang University of Science and Technology (POSTECH), ; Pohang, 37673 Republic of Korea
                [2 ]GRID grid.264381.a, ISNI 0000 0001 2181 989X, Department of Biophysics, Institute of Quantum Biophysics, , Sungkyunkwan University, ; Suwon, 16419 Republic of Korea
                [3 ]GRID grid.264381.a, ISNI 0000 0001 2181 989X, Department of Intelligent Precision Healthcare Convergence, , Sungkyunkwan University, ; Suwon, 16419 Republic of Korea
                [4 ]GRID grid.49100.3c, ISNI 0000 0001 0742 4007, Department of Chemical Engineering, , Pohang University of Science and Technology (POSTECH), ; Pohang, 37673 Republic of Korea
                [5 ]GRID grid.49100.3c, ISNI 0000 0001 0742 4007, Department of Electrical Engineering, , Pohang University of Science and Technology (POSTECH), ; Pohang, 37673 Republic of Korea
                [6 ]GRID grid.480377.f, ISNI 0000 0000 9113 9200, POSCO-POSTECH-RIST Convergence Research Center for Flat Optics and Metaphotonics, ; Pohang, 37673 Republic of Korea
                [7 ]GRID grid.49100.3c, ISNI 0000 0001 0742 4007, National Institute of Nanomaterials Technology (NINT), ; Pohang, 37673 Republic of Korea
                Author information
                http://orcid.org/0000-0001-9458-6062
                http://orcid.org/0000-0002-0827-1919
                http://orcid.org/0000-0001-8686-6670
                http://orcid.org/0000-0002-4420-3489
                http://orcid.org/0000-0002-2179-2890
                Article
                806
                10.1038/s41377-022-00806-8
                9054757
                35487908
                79dca088-660e-43c7-8921-bf0f28f29727
                © The Author(s) 2022

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 12 October 2021
                : 11 April 2022
                : 18 April 2022
                Funding
                Funded by: FundRef https://doi.org/10.13039/501100003725, National Research Foundation of Korea (NRF);
                Award ID: NRF-2019R1A2C3003129
                Award ID: CAMM-2019M3A6B3030637
                Award ID: NRF-2019R1A5A8080290
                Award ID: NRF-2020K1A3A1A21024374
                Award ID: NRF-2021K2A9A2A15000174
                Award ID: NRF-2021K1A3A1A17086079
                Award ID: NRF-2021R1C1C2004291
                Award ID: NRF-2021R1A4A1030944
                Award ID: NRF-2021R1A2C2095010
                Award Recipient :
                Funded by: FundRef https://doi.org/10.13039/100004358, Samsung;
                Award ID: SRFC-IT1901-05
                Award Recipient :
                Funded by: FundRef https://doi.org/10.13039/501100002541, Pohang University of Science and Technology (POSTECH);
                Award ID: Alchemist fellowship
                Award Recipient :
                Categories
                Article
                Custom metadata
                © The Author(s) 2022

                metamaterials,liquid crystals,nanophotonics and plasmonics,micro-optics

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