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      Leaching of Carbon Reinforced Concrete—Part 1: Experimental Investigations

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          Abstract

          The composite material ‘carbon concrete composite (C 3)’ is currently capturing the building sector as an ‘innovative’ and ‘sustainable’ alternative to steel reinforced concrete. In this work, its environmental compatibility was investigated. The focus of this research was the leaching behavior of C 3, especially for the application as irrigated façade elements. Laboratory and outdoor exposure tests were run to determine and assess the heavy metal and trace element emissions. In the wake of this work, the validity of laboratory experiments and the transferability to outdoor behavior were investigated. The experimental results show very low releases of environmental harmful substances from carbon concrete composite. Most heavy metal concentrations were in the range of <0.1–8 µg/L, and higher concentrations (up to 32 µg/L) were found for barium, chromium, and copper. Vanadium and zinc concentrations were in the range of 0.1–60 µg/L, boron and nickel concentrations were clearly exceeding 100 µg/L. Most of the high concentrations were found to be a result of the rainfall background concentrations. The material C 3 is therefore considered to be environmentally friendly. There is no general correlation between laboratory leaching data and outdoor emissions. The results depend on the examined substance and used method. The prediction and evaluation of the leaching of building elements submitted to rain is therefore challenging. This topic is debated in the second part of this publication.

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          THE DISTRIBUTION OF RAINDROPS WITH SIZE

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            Micropollutants in urban stormwater: occurrence, concentrations, and atmospheric contributions for a wide range of contaminants in three French catchments.

            This study aimed at: (a) providing information on the occurrence and concentration ranges in urban stormwater for a wide array of pollutants (n = 77); (b) assessing whether despite the differences between various catchments (land use, climatic conditions, etc.), the trends in terms of contamination level are similar; and (c) analyzing the contribution of total atmospheric fallout (TAF) with respect to sources endogenous to this contamination. The studied contaminants include conventional stormwater contaminants (polycyclic aromatic hydrocarbons (PAHs), Zn, Cu, Pb, etc.), in addition to poorly or undocumented pollutants such as nonylphenol and octylphenol ethoxylates (NPnEO and OPnEO), bisphenol A (BPA), polybrominated diphenyl ethers (PBDEs), a wide variety of pesticides, and various metals of relevance (As, Ti, Sr, V). Sampling and analysis were performed using homogeneous methods on three urban catchments with different land use patterns located in three distinct French towns. For many of these pollutants, the results do not allow highlighting a significant difference in stormwater quality at the scale of the three urban catchments considered. Significant differences were, however, observed for several metals (As, Cr, Cu, Ni, Sr and Zn), PAHs, and PBDEs, though this assessment would need to be confirmed by further experiments. The pollutant distributions between dissolved and particulate phases were found to be similar across the three experimental sites, thus suggesting no site dependence. Lastly, the contributions of TAF to stormwater contamination for micropollutants were quite low. This finding held true not only for PAHs, as previously demonstrated in the literature, but also for a broader range of molecules such as BPA, NPnEO, OPnEO, and PBDEs, whose high local production is correlated with the leaching of urban surfaces, buildings, and vehicles.
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              Leaching of biocides used in façade coatings under laboratory test conditions.

              The European Biocidal Products Directive 98/8/EC requires a risk assessment concerning possible effects of active ingredients on the environment. Biocides can be leached from treated materials exposed to outdoor use. These emissions have to be estimated and evaluated during the authorization procedure. Different immersion and irrigation tests were performed to investigate leaching of biocides from façade coatings. Several marketed formulations of textured coatings and paints spiked with a mixture of commonly used active ingredients (OIT, DCOIT, IPBC, carbendazim, isoproturon, diuron, terbutryn, and Irgarol 1051) were investigated. The emission process can be described by time-dependent functions that depend on the test conditions. The results of all test procedures confirm that leachability is related to water solubility and n-octanol-water partition coefficient of the active ingredients and that leaching of biocides from façade coatings is mainly a diffusion controlled process. Other factors like the composition of the product, availability and transport of water, concentration of active ingredients in the coatings, as well as UV-exposure of the coatings influence biocide emissions.
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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                02 October 2020
                October 2020
                : 13
                : 19
                : 4405
                Affiliations
                Institute of Building Materials Research, RWTH (Rheinisch-Westfälische Technische Hochschule) Aachen University, 52062 Aachen, Germany; vollpracht@ 123456ibac.rwth-aachen.de
                Author notes
                [* ]Correspondence: weiler@ 123456ibac.rwth-aachen.de ; Tel.: +49-241-8095134
                Author information
                https://orcid.org/0000-0003-4743-4079
                https://orcid.org/0000-0002-9950-5046
                Article
                materials-13-04405
                10.3390/ma13194405
                7579653
                33023251
                7755eaf1-dd60-40bf-abb9-7d29ea8eb534
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 07 September 2020
                : 30 September 2020
                Categories
                Article

                leaching,carbon concrete composite,irrigated construction elements,environmental compatibility,irrigated building materials

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