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      Effect of UV Radiation on Optical Properties and Hardness of Transparent Wood

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          Abstract

          Optically transparent wood is a type of composite material, combining wood as a renewable resource with the optical and mechanical properties of synthetic polymers. During this study, the effect of monochromatic UV-C (λ—250 nm) radiation on transparent wood was evaluated. Samples of basswood were treated using a lignin modification method, to preserve most of the lignin, and subsequently impregnated with refractive-index-matched types of acrylic polymers (methyl methacrylate, 2-hydroxyethyl methacrylate). Optical (transmittance, colour) and mechanical (shore D hardness) properties were measured to describe the degradation process over 35 days. The transmittance of the samples was significantly decreased during the first seven days (12% EMA, 15% MMA). The average lightness of both materials decreased by 10% (EMA) and 17% (MMA), and the colour shifted towards a red and yellow area of CIE L*a*b* space coordinates. The influence of UV-C radiation on the hardness of the samples was statistically insignificant (W+MMA 84.98 ± 2.05; W+EMA 84.89 ± 2.46), therefore the hardness mainly depends on the hardness of used acrylic polymer. The obtained results can be used to assess the effect of disinfection of transparent wood surfaces with UV-C radiation (e.g., due to inactivation of SARS-CoV-2 virus) on the change of its aesthetic and mechanical properties.

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          A radiative cooling structural material

          Reducing human reliance on energy-inefficient cooling methods such as air conditioning would have a large impact on the global energy landscape. By a process of complete delignification and densification of wood, we developed a structural material with a mechanical strength of 404.3 megapascals, more than eight times that of natural wood. The cellulose nanofibers in our engineered material backscatter solar radiation and emit strongly in mid-infrared wavelengths, resulting in continuous subambient cooling during both day and night. We model the potential impact of our cooling wood and find energy savings between 20 and 60%, which is most pronounced in hot and dry climates.
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            Highly Anisotropic, Highly Transparent Wood Composites

            For the first time, two types of highly anisotropic, highly transparent wood composites are demonstrated by taking advantage of the macro-structures in original wood. These wood composites are highly transparent with a total transmittance up to 90% but exhibit dramatically different optical and mechanical properties.
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              Optically Transparent Wood from a Nanoporous Cellulosic Template: Combining Functional and Structural Performance.

              Optically transparent wood (TW) with transmittance as high as 85% and haze of 71% was obtained using a delignified nanoporous wood template. The template was prepared by removing the light-absorbing lignin component, creating nanoporosity in the wood cell wall. Transparent wood was prepared by successful impregnation of lumen and the nanoscale cellulose fiber network in the cell wall with refractive-index-matched prepolymerized methyl methacrylate (MMA). During the process, the hierarchical wood structure was preserved. Optical properties of TW are tunable by changing the cellulose volume fraction. The synergy between wood and PMMA was observed for mechanical properties. Lightweight and strong transparent wood is a potential candidate for lightweight low-cost, light-transmitting buildings and transparent solar cell windows.
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Polymers (Basel)
                Polymers (Basel)
                polymers
                Polymers
                MDPI
                2073-4360
                23 June 2021
                July 2021
                : 13
                : 13
                : 2067
                Affiliations
                Department of Integrated Safety, Faculty of Materials Science and Technology in Trnava, Slovak University of Technology in Bratislava, Botanická 49, 917 24 Trnava, Slovakia; tomas.stefko@ 123456stuba.sk (T.Š.); peter.rantuch@ 123456stuba.sk (P.R.); jozef.martinka@ 123456stuba.sk (J.M.); alica.pastierova@ 123456stuba.sk (A.P.)
                Author notes
                [* ]Correspondence: igor.wachter@ 123456stuba.sk ; Tel.: +421-904-398-793
                Author information
                https://orcid.org/0000-0003-0691-0462
                https://orcid.org/0000-0001-5826-8323
                https://orcid.org/0000-0002-0060-5785
                Article
                polymers-13-02067
                10.3390/polym13132067
                8271824
                34201886
                f625f4cc-6f78-4511-a7b6-92445359b121
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 31 May 2021
                : 21 June 2021
                Categories
                Article

                transparent wood,uv-c radiation,optical properties,basswood,hardness,chromophores deactivation

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