Photoinduced Cross-Coupling of Aryl Iodides with Alkenes.

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Abstract

A protocol for photoinduced cross-coupling of aryl iodides having polar π-functional groups or elongated π-conjugation with alkenes has been developed. The radical cascade mechanism involving generation of aryl radicals via C-I bond homolysis of photoexcited aryl iodides and their subsequent addition to alkenes is proposed. The method enables iodide-selective cross-coupling over other halogen leaving groups with functional group compatibility on both arene and alkene motifs.

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Journal

Journal ID (iso-abbrev): Org Lett

Title: Organic letters

Publisher: American Chemical Society (ACS)

ISSN (Electronic): 1523-7052

ISSN (Print): 1523-7052

Publication date (Electronic): Jan 15 2021

Volume: 23

Issue: 2

Affiliations

[1 ] Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Article

DOI: 10.1021/acs.orglett.0c03935

PubMed ID: 33404249

SO-VID: eeafdcae-eaed-40e9-9ff2-4e1c2aec3c77

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