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      Field‐Based Evidence for Intra‐Slab High‐Permeability Channel Formation at Eclogite‐Facies Conditions During Subduction

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          Abstract

          Fluid release from subducting oceanic lithosphere is a key process for subduction zone geodynamics, from controlling arc volcanism to seismicity and tectonic exhumation. However, many fundamental details of fluid composition, flow pathways, and reactivity with slab‐forming rocks remain to be thoroughly understood. In this study we investigate a multi‐kilometer‐long, high‐pressure metasomatic system preserved in the lawsonite‐eclogite metamorphic unit of Alpine Corsica, France. The fluid‐mediated process was localized along a major intra‐slab interface, which is the contact between basement and cover unit. Two distinct metasomatic stages are identified and discussed. We show that these two stages resulted from the infiltration of deep fluids that were derived from the same source and had the same slab‐parallel, updip flow direction. By mass balance analysis, we quantify metasomatic mass changes along this fluid pathway and the time‐integrated fluid fluxes responsible for them. In addition, we also assess carbon fluxes associated with these metasomatic events. The magnitude of the estimated fluid fluxes (10 4–10 5) indicates that major intra‐slab interfaces such as lithological boundaries acted as fluid channels facilitating episodic pulses of fluid flow. We also show that when fluids are channelized, high time‐integrated fluid fluxes lead to carbon fluxes several orders of magnitude higher than carbon fluxes generated by local dehydration reactions. Given the size and geologic features of the investigated metasomatic system, we propose that it represents the first reported natural analogue of the so‐called high permeability channels predicted by numerical simulations.

          Key Points

          • Analysis of metasomatic rocks formed along a slab‐scale lithological interface indicates that extremely high fluid fluxes were realized

          • Reactive fluid flow lead to CO 2‐rock interactions, which can sequester as much carbon as the amount liberated from decarbonation/dissolution

          • The investigated metasomatic system is the first report of a natural analogue of intra‐slab high permeability channel

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          Most cited references97

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          The Generation and Compaction of Partially Molten Rock

          D MCKENZIE (1984)
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            Serpentine stability to mantle depths and subduction-related magmatism.

            Results of high-pressure experiments on samples of hydrated mantle rocks show that the serpentine mineral antigorite is stable to approximately 720 degrees C at 2 gigapascals, to approximately 690 degrees C at 3 gigapascals, and to approximately 620 degrees C at 5 gigapascals. The breakdown of antigorite to forsterite plus enstatite under these conditions produces 13 percent H(2)O by weight to depths of 150 to 200 kilometers in subduction zones. This H(2)O is in an ideal position for ascent into the hotter, overlying mantle where it can cause partial melting in the source region for calc-alkaline magmas at a depth of 100 to 130 kilometers and a temperature of approximately 1300 degrees C. The breakdown of antigorite in hydrated mantle produces an order of magnitude more H(2)O than does the dehydration of altered oceanic crust.
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              Geochemical and geodynamical constraints on subduction zone magmatism

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                Author and article information

                Contributors
                francesca.piccoli@geo.unibe.ch
                Journal
                Geochem Geophys Geosyst
                Geochem Geophys Geosyst
                10.1002/(ISSN)1525-2027
                GGGE
                Geochemistry, Geophysics, Geosystems : G(3)
                John Wiley and Sons Inc. (Hoboken )
                1525-2027
                23 March 2021
                March 2021
                : 22
                : 3 ( doiID: 10.1002/ggge.v22.3 )
                : e2020GC009520
                Affiliations
                [ 1 ] Insitut de Minéralogie Physique des Matériaux et Cosmochimie (IMPMC) UMR7590 CNRS‐UPMC‐MNHN‐IRD Paris France
                [ 2 ] Institute of Geological Sciences University of Bern Baltzerstrasse Bern Switzerland Switzerland
                [ 3 ] Department of Geology and Geophysics Yale University New Haven CT USA
                [ 4 ] Peabody Museum of Natural History Yale University New Haven CT USA
                [ 5 ] Department of Earth Sciences University of Toronto Toronto Canada
                [ 6 ] Center for Space and Habitability University of Bern Bern Switzerland
                [ 7 ] Dipartimento di Scienze Biologiche Geologiche e Ambientali Alma Mater Studiorum Università di Bologna Bologna Italy
                Author notes
                [*] [* ] Correspondence to:

                F. Piccoli,

                francesca.piccoli@ 123456geo.unibe.ch

                Author information
                https://orcid.org/0000-0001-9941-0103
                https://orcid.org/0000-0001-8408-0279
                https://orcid.org/0000-0002-6816-1076
                https://orcid.org/0000-0002-7384-8577
                https://orcid.org/0000-0001-8892-9567
                Article
                GGGE22447 2020GC009520
                10.1029/2020GC009520
                8047908
                ec1a5d81-b3c5-4a03-b9e3-d363c6b131cb
                © 2021. The Authors.

                This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

                History
                : 01 February 2021
                : 10 November 2020
                : 03 February 2021
                Page count
                Figures: 6, Tables: 3, Pages: 17, Words: 10717
                Funding
                Funded by: National Science Foundation (NSF) , open-funder-registry 10.13039/100000001;
                Award ID: EAR‐1650329
                Funded by: University Pierre et Marie Curie (Paris 6, Sorbonne Universités)
                Funded by: ANR T‐ERC
                Award ID: LS 171301
                Award ID: INSU‐SYSTER MIUR
                Funded by: Deep Carbon Observatory (DCO) Deep Energy community
                Funded by: Richard Lounsbery foundation
                Funded by: CSH fellowship at University of Bern
                Categories
                Geochemistry
                Subduction Zone Processes
                Marine Geology and Geophysics
                Subduction Zone Processes
                Mineralogy and Petrology
                Subduction Zone Processes
                Tectonophysics
                Subduction Zone Processes
                Volcanology
                Subduction Zone Processes
                Research Article
                Research Article
                Custom metadata
                2.0
                March 2021
                Converter:WILEY_ML3GV2_TO_JATSPMC version:6.0.2 mode:remove_FC converted:15.04.2021

                carbon fluxes,fluid migration,metasomatism,subduction high‐permeability channels

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