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      Potential use of kraft and organosolv lignins as a natural additive for healthcare products†

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      RSC Advances
      The Royal Society of Chemistry

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          Abstract

          The growing interest in substituting synthetic products coming from non-renewable sources with products from biomass has focused attention on the lignin biopolymer. Its high availability, low price and properties make the development of new and valuable uses for lignin interesting, thus improving the economic and environmental aspects of the biomass conversion. To achieve this objective, the potential use of industrial kraft and organosolv lignins as antioxidants, antimicrobials and sunscreen products has been evaluated. The results of a detailed antibacterial and antifungal study demonstrated the high potential of kraft lignins against a variety of foodborne and human pathogenic microorganisms. Moreover, both organosolv and kraft lignins presented an effective protection factor (SPF values from 10–20), demonstrating their effectiveness as natural additives for the sun lotion market. In addition, lignin samples presented high antioxidant capacity compared to butylated hydroxytoluene (BHT), one common commercial antioxidant industrially used. Therefore, the development of innovative applications of lignins as a commodity for the chemical, pharmaceutical or cosmetic industries could expand their possible uses in the market giving new added values to lignin.

          Abstract

          New opportunities for industrial and lab-scale isolated lignin as an antioxidant, antimicrobial and sunscreen product.

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          Most cited references41

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          Use of a free radical method to evaluate antioxidant activity

          LWT - Food Science and Technology, 28(1), 25-30
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            Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy

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              Organosolv ethanol lignin from hybrid poplar as a radical scavenger: relationship between lignin structure, extraction conditions, and antioxidant activity.

              Twenty-one organosolv ethanol lignin samples were prepared from hybrid poplar (Populus nigra xP. maximowiczii) under varied conditions with an experimental matrix designed using response surface methodology (RSM). The lignin preparations were evaluated as potential antioxidants. Results indicated that the lignins with more phenolic hydroxyl groups, less aliphatic hydroxyl groups, low molecular weight, and narrow polydispersity showed high antioxidant activity. Processing conditions affected the functional groups and molecular weight of the extracted organosolv ethanol lignins, and consequently influenced the antioxidant activity of the lignins. In general, the lignins prepared at elevated temperature, longer reaction time, increased catalyst, and diluted ethanol showed high antioxidant activity. Regression models were developed to enable the quantitative prediction of lignin characteristics and antioxidant activity based on the processing conditions.
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                Author and article information

                Journal
                RSC Adv
                RSC Adv
                RA
                RSCACL
                RSC Advances
                The Royal Society of Chemistry
                2046-2069
                10 July 2018
                2 July 2018
                10 July 2018
                : 8
                : 43
                : 24525-24533
                Affiliations
                [a] Chemical and Environmental Engineering Department, University of the Basque Country Plaza Europa, 1 20018 Donostia-San Sebastián Spain jalel.labidi@ 123456ehu.eus
                [b] Laboratory of Materials and Molecules Application, University of Tunisia El Manar, Farhat Hached University Campus PB 94 – Rommana 1068 Tunis Tunisia
                [c] Ömer Halisdemir University, Central Research Laboratory TR-51240, Niğde Turkey
                [d] Department of Biotechnology and Molecular Biology, Faculty of Science and Letters, Aksaray University Aksaray Turkey
                Author information
                https://orcid.org/0000-0001-6954-2703
                https://orcid.org/0000-0002-8382-9492
                Article
                c8ra02255k
                10.1039/c8ra02255k
                9082055
                35539196
                d94cb90b-171d-4243-bffd-bac55a901d80
                This journal is © The Royal Society of Chemistry
                History
                : 14 March 2018
                : 30 June 2018
                Page count
                Pages: 9
                Funding
                Funded by: Eusko Jaurlaritza, doi 10.13039/501100003086;
                Award ID: IT1008-16
                Funded by: Euskal Herriko Unibertsitatea, doi 10.13039/501100003451;
                Award ID: PIF 13/050
                Categories
                Chemistry
                Custom metadata
                Paginated Article

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