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      Hydrophobic Metal–Organic Frameworks

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          Functional Porous Coordination Polymers

          The chemistry of the coordination polymers has in recent years advanced extensively, affording various architectures, which are constructed from a variety of molecular building blocks with different interactions between them. The next challenge is the chemical and physical functionalization of these architectures, through the porous properties of the frameworks. This review concentrates on three aspects of coordination polymers: 1). the use of crystal engineering to construct porous frameworks from connectors and linkers ("nanospace engineering"), 2). characterizing and cataloging the porous properties by functions for storage, exchange, separation, etc., and 3). the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli. Our aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers.
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            Wetting: statics and dynamics

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              Stable Metal-Organic Frameworks: Design, Synthesis, and Applications

              Metal-organic frameworks (MOFs) are an emerging class of porous materials with potential applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous advantages, applications of many MOFs are ultimately limited by their stability under harsh conditions. Herein, the recent advances in the field of stable MOFs, covering the fundamental mechanisms of MOF stability, design, and synthesis of stable MOF architectures, and their latest applications are reviewed. First, key factors that affect MOF stability under certain chemical environments are introduced to guide the design of robust structures. This is followed by a short review of synthetic strategies of stable MOFs including modulated synthesis and postsynthetic modifications. Based on the fundamentals of MOF stability, stable MOFs are classified into two categories: high-valency metal-carboxylate frameworks and low-valency metal-azolate frameworks. Along this line, some representative stable MOFs are introduced, their structures are described, and their properties are briefly discussed. The expanded applications of stable MOFs in Lewis/Brønsted acid catalysis, redox catalysis, photocatalysis, electrocatalysis, gas storage, and sensing are highlighted. Overall, this review is expected to guide the design of stable MOFs by providing insights into existing structures, which could lead to the discovery and development of more advanced functional materials.
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                Author and article information

                Journal
                Advanced Materials
                Adv. Mater.
                Wiley
                0935-9648
                1521-4095
                June 03 2019
                June 03 2019
                : 1900820
                Affiliations
                [1 ]Department of Chemistry and Catalysis Research CentreTechnical University of Munich 85748 Garching Germany
                [2 ]Regional Centre of Advanced Technologies and MaterialsFaculty of SciencePalacky University Šlechtitelu˚ 27 783 71 Olomouc Czech Republic
                [3 ]Max Planck Institute for Polymer Research Ackermannweg 10 55128 Mainz Germany
                [4 ]Sandia National Laboratories 7011 East Avenue Livermore CA 94551 USA
                Article
                10.1002/adma.201900820
                31155761
                d74232db-7a45-42b2-8c3a-227c9f384623
                © 2019

                http://doi.wiley.com/10.1002/tdm_license_1.1

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