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      Two-billion-year-old volcanism on the Moon from Chang’e-5 basalts

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          Abstract

          The Moon has a magmatic and thermal history that is distinct from that of the terrestrial planets 1 . Radioisotope dating of lunar samples suggests that most lunar basaltic magmatism ceased by around 2.9–2.8 billion years ago (Ga) 2, 3 , although younger basalts between 3 Ga and 1 Ga have been suggested by crater-counting chronology, which has large uncertainties owing to the lack of returned samples for calibration 4, 5 . Here we report a precise lead–lead age of 2,030 ± 4 million years ago for basalt clasts returned by the Chang’e-5 mission, and a 238U/ 204Pb ratio ( µ value) 6 of about 680 for a source that evolved through two stages of differentiation. This is the youngest crystallization age reported so far for lunar basalts by radiometric dating, extending the duration of lunar volcanism by approximately 800–900 million years. The µ value of the Chang’e-5 basalt mantle source is within the range of low-titanium and high-titanium basalts from Apollo sites ( µ value of about 300–1,000), but notably lower than those of potassium, rare-earth elements and phosphorus (KREEP) and high-aluminium basalts 7 ( µ value of about 2,600–3,700), indicating that the Chang’e-5 basalts were produced by melting of a KREEP-poor source. This age provides a pivotal calibration point for crater-counting chronology in the inner Solar System and provides insight on the volcanic and thermal history of the Moon.

          Abstract

          Basalt samples returned from the Moon by the Chang’e-5 mission are revealed to be two billion years old by radioisotopic dating, providing insight on the volcanic history of the Moon.

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          Subcommission on geochronology: Convention on the use of decay constants in geo- and cosmochronology

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            Late formation and prolonged differentiation of the Moon inferred from W isotopes in lunar metals.

            The Moon is thought to have formed from debris ejected by a giant impact with the early 'proto'-Earth and, as a result of the high energies involved, the Moon would have melted to form a magma ocean. The timescales for formation and solidification of the Moon can be quantified by using 182Hf-182W and 146Sm-142Nd chronometry, but these methods have yielded contradicting results. In earlier studies, 182W anomalies in lunar rocks were attributed to decay of 182Hf within the lunar mantle and were used to infer that the Moon solidified within the first approximately 60 million years of the Solar System. However, the dominant 182W component in most lunar rocks reflects cosmogenic production mainly by neutron capture of 181Ta during cosmic-ray exposure of the lunar surface, compromising a reliable interpretation in terms of 182Hf-182W chronometry. Here we present tungsten isotope data for lunar metals that do not contain any measurable Ta-derived 182W. All metals have identical 182W/184W ratios, indicating that the lunar magma ocean did not crystallize within the first approximately 60 Myr of the Solar System, which is no longer inconsistent with Sm-Nd chronometry. Our new data reveal that the lunar and terrestrial mantles have identical 182W/184W. This, in conjunction with 147Sm-143Nd ages for the oldest lunar rocks, constrains the age of the Moon and Earth to Myr after formation of the Solar System. The identical 182W/184W ratios of the lunar and terrestrial mantles require either that the Moon is derived mainly from terrestrial material or that tungsten isotopes in the Moon and Earth's mantle equilibrated in the aftermath of the giant impact, as has been proposed to account for identical oxygen isotope compositions of the Earth and Moon.
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              The isotopic record of lunar volcanism

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                Author and article information

                Contributors
                licl@nao.cas.cn
                lixh@gig.ac.cn
                Journal
                Nature
                Nature
                Nature
                Nature Publishing Group UK (London )
                0028-0836
                1476-4687
                19 October 2021
                19 October 2021
                2021
                : 600
                : 7887
                : 54-58
                Affiliations
                [1 ]GRID grid.9227.e, ISNI 0000000119573309, State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, , Chinese Academy of Sciences, ; Beijing, China
                [2 ]GRID grid.9227.e, ISNI 0000000119573309, Key Laboratory of Lunar and Deep Space Exploration, National Astronomical Observatories, , Chinese Academy of Sciences, ; Beijing, China
                [3 ]GRID grid.12981.33, ISNI 0000 0001 2360 039X, Planetary Environmental and Astrobiological Research Laboratory, School of Atmospheric Sciences, , Sun Yat-sen University, ; Zhuhai, China
                [4 ]GRID grid.9227.e, ISNI 0000000119573309, Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, , Chinese Academy of Sciences, ; Beijing, China
                [5 ]GRID grid.9227.e, ISNI 0000000119573309, Center for Lunar and Planetary Sciences, Institute of Geochemistry, , Chinese Academy of Sciences, ; Guiyang, China
                Author information
                http://orcid.org/0000-0002-7280-5508
                http://orcid.org/0000-0001-8562-9737
                http://orcid.org/0000-0001-7195-7393
                http://orcid.org/0000-0002-5026-6937
                http://orcid.org/0000-0002-3407-4329
                http://orcid.org/0000-0001-8215-8271
                http://orcid.org/0000-0001-7754-9390
                http://orcid.org/0000-0002-0439-0507
                http://orcid.org/0000-0002-2476-1635
                http://orcid.org/0000-0002-1845-7565
                http://orcid.org/0000-0001-9628-9838
                http://orcid.org/0000-0002-2281-7885
                http://orcid.org/0000-0002-0817-2742
                http://orcid.org/0000-0001-5512-7736
                Article
                4100
                10.1038/s41586-021-04100-2
                8636262
                34666338
                873122af-c9c8-4e70-bc9c-1064b8e389db
                © The Author(s) 2021

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 28 July 2021
                : 6 October 2021
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                Custom metadata
                © The Author(s), under exclusive licence to Springer Nature Limited 2021

                Uncategorized
                geochemistry,rings and moons
                Uncategorized
                geochemistry, rings and moons

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