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      Exceptional water production yield enabled by batch-processed portable water harvester in semi-arid climate

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          Abstract

          Sorption-based atmospheric water harvesting has the potential to realize water production anytime, anywhere, but reaching a hundred-gram high water yield in semi-arid climates is still challenging, although state-of-the-art sorbents have been used. Here, we report a portable and modularized water harvester with scalable, low-cost, and lightweight LiCl-based hygroscopic composite (Li-SHC) sorbents. Li-SHC achieves water uptake capacity of 1.18, 1.79, and 2.93 g g −1 at 15%, 30%, and 60% RH, respectively. Importantly, considering the large mismatch between water capture and release rates, a rationally designed batch processing mode is proposed to pursue maximum water yield in a single diurnal cycle. Together with the advanced thermal design, the water harvester shows an exceptional water yield of 311.69 g day −1 and 1.09 g g sorbent −1 day −1 in the semi-arid climate with the extremely low RH of ~15%, demonstrating the adaptability and possibility of achieving large-scale and reliable water production in real scenarios.

          Abstract

          Sorption-based atmospheric water harvesting has the potential to realize flexible water production but reaching high water yield in semi-arid climate is still challenging. Here, the authors report a portable and modularized water harvester with scalable, low-cost, and lightweight hygroscopic composite sorbent which shows an exceptional water production in semi-arid climate with low relative humidity of 15%.

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          Four billion people facing severe water scarcity

          Global water scarcity assessment at a high spatial and temporal resolution, accounting for environmental flow requirements.
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            Water harvesting from air with metal-organic frameworks powered by natural sunlight.

            Atmospheric water is a resource equivalent to ~10% of all fresh water in lakes on Earth. However, an efficient process for capturing and delivering water from air, especially at low humidity levels (down to 20%), has not been developed. We report the design and demonstration of a device based on a porous metal-organic framework {MOF-801, [Zr6O4(OH)4(fumarate)6]} that captures water from the atmosphere at ambient conditions by using low-grade heat from natural sunlight at a flux of less than 1 sun (1 kilowatt per square meter). This device is capable of harvesting 2.8 liters of water per kilogram of MOF daily at relative humidity levels as low as 20% and requires no additional input of energy.
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              MOF water harvesters

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                Author and article information

                Contributors
                sailote@sjtu.edu.cn
                rzwang@sjtu.edu.cn
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                15 September 2022
                15 September 2022
                2022
                : 13
                : 5406
                Affiliations
                [1 ]GRID grid.16821.3c, ISNI 0000 0004 0368 8293, Institute of Refrigeration and Cryogenics, , Shanghai Jiao Tong University, ; Shanghai, 200240 China
                [2 ]GRID grid.16821.3c, ISNI 0000 0004 0368 8293, Engineering Research Center of Solar Power & Refrigeration, MOE China, ; Shanghai, 200240 China
                Author information
                http://orcid.org/0000-0002-9105-3006
                http://orcid.org/0000-0002-0875-8428
                http://orcid.org/0000-0003-3586-5728
                Article
                33062
                10.1038/s41467-022-33062-w
                9478113
                36109494
                21ff23c4-dfb3-4c25-845f-247ba019a26e
                © The Author(s) 2022

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 28 January 2022
                : 31 August 2022
                Funding
                Funded by: FundRef https://doi.org/10.13039/501100001809, National Natural Science Foundation of China (National Science Foundation of China);
                Award ID: 51521004
                Award Recipient :
                Categories
                Article
                Custom metadata
                © The Author(s) 2022

                Uncategorized
                polymers,mechanical engineering,synthesis and processing
                Uncategorized
                polymers, mechanical engineering, synthesis and processing

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