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      Net-zero transition of the global chemical industry with CO 2-feedstock by 2050: feasible yet challenging†

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      Green Chemistry
      The Royal Society of Chemistry

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          Abstract

          Carbon capture, utilization and storage (CCUS) have been projected by the power and industrial sectors to play a vital role towards net-zero greenhouse gas emissions. In this study, we aim to explore the feasibility of a global chemical industry that fully relies on CO 2 as its carbon source in 2050. We project the global annual CO 2 demand as chemical feedstock to be 2.2–3.1 gigatonnes (Gt), well within the possible range of supply (5.2–13.9 Gt) from the power, cement, steel, and kraft pulp sectors. Hence, feedstock availability is not a constraint factor for the transition towards a fully CO 2-based chemical industry on the global basis, with the exception of few regions that could face local supply shortages, such as the Middle East. We further conduct life cycle assessment to examine the environmental benefits on climate change and the trade-offs of particulate matter-related health impacts induced by carbon capture. We conclude that CO 2 captured from solid biomass-fired power plants and kraft pulp mills in Europe would have the least environmental and health impacts, and that India and China should prioritize low-impact regional electricity supply before a large-scale deployment of CCUS. Finally, two bottom-up case studies of China and the Middle East illustrate how the total regional environmental and health impacts from carbon capture can be minimized by optimizing its supply sources and transport, requiring cross-sectoral cooperation and early planning of infrastructure. Overall, capture and utilization of unabatable industrial waste CO 2 as chemical feedstock can be a feasible way for the net-zero transition of the industry, while concerted efforts are yet needed to build up the carbon-capture-and-utilization value chain around the world.

          Abstract

          This study supports the net-zero transition of the global chemical industry by 2050, especially demonstrating the regional CO 2 supply-demand feasibility and providing novel guidance regarding site selection and supply-chain optimization.

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          Most cited references104

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          Carbon capture and storage (CCS): the way forward

          Carbon capture and storage (CCS) is vital to climate change mitigation, and has application across the economy, in addition to facilitating atmospheric carbon dioxide removal resulting in emissions offsets and net negative emissions. This contribution reviews the state-of-the-art and identifies key challenges which must be overcome in order to pave the way for its large-scale deployment. Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets, delivering low carbon heat and power, decarbonising industry and, more recently, its ability to facilitate the net removal of CO 2 from the atmosphere. However, despite this broad consensus and its technical maturity, CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus, in this paper we review the current state-of-the-art of CO 2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C, we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS), and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS, we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas, we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.
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            Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment

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              The technological and economic prospects for CO2 utilization and removal

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                Author and article information

                Journal
                Green Chem
                Green Chem
                GC
                GRCHFJ
                Green Chemistry
                The Royal Society of Chemistry
                1463-9262
                1463-9262
                30 November 2022
                3 January 2023
                30 November 2022
                : 25
                : 1
                : 415-430
                Affiliations
                [a] Chair of Ecological Systems Design, Institute of Environmental Engineering, ETH Zürich John-von-Neumann-Weg 9 8093 Zürich Switzerland jhuo@ 123456ethz.ch
                [b] National Centre of Competence in Research (NCCR) Catalysis, ETH Zürich Zürich Switzerland
                [c] Empa-Swiss Federal Laboratories for Materials Science and Technology, Technology and Society Laboratory Lerchenfeldstrasse 5 CH-9014 St Gallen Switzerland
                [d] Sustainable Process Systems Engineering Lab, Department of Chemistry and Applied Biosciences, ETH Zürich Vladimir-Prelog-Weg 1 8093 Zürich Switzerland
                Author information
                https://orcid.org/0000-0003-2079-0591
                https://orcid.org/0000-0001-9914-7659
                https://orcid.org/0000-0002-8411-5504
                https://orcid.org/0000-0001-6074-8473
                https://orcid.org/0000-0001-6376-9878
                Article
                d2gc03047k
                10.1039/d2gc03047k
                9808895
                36685711
                10f64a36-9012-45b0-b8fb-dbac99d9f8f3
                This journal is © The Royal Society of Chemistry
                History
                : 15 August 2022
                : 28 November 2022
                Page count
                Pages: 16
                Funding
                Funded by: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, doi 10.13039/501100001711;
                Award ID: 180544
                Categories
                Chemistry
                Custom metadata
                Paginated Article

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