ExoMol molecular line lists V: the ro-vibrational spectra of NaCl and KCl

The discovery of a plume of water vapour and ice particles emerging from warm fractures ('tiger stripes') in Saturn's small, icy moon Enceladus raised the question of whether the plume emerges from a subsurface liquid source or from the decomposition of ice. Previous compositional analyses of particles injected by the plume into Saturn's diffuse E ring have already indicated the presence of liquid water, but the mechanisms driving the plume emission are still debated. Here we report an analysis of the composition of freshly ejected particles close to the sources. Salt-rich ice particles are found to dominate the total mass flux of ejected solids (more than 99 per cent) but they are depleted in the population escaping into Saturn's E ring. Ice grains containing organic compounds are found to be more abundant in dense parts of the plume. Whereas previous Cassini observations were compatible with a variety of plume formation mechanisms, these data eliminate or severely constrain non-liquid models and strongly imply that a salt-water reservoir with a large evaporating surface provides nearly all of the matter in the plume.

Recent surveys have revealed that planets intermediate in size between Earth and Neptune ("super-Earths") are among the most common planets in the Galaxy. Atmospheric studies are the next step toward developing a comprehensive understanding of this new class of object. Much effort has been focused on using transmission spectroscopy to characterize the atmosphere of the super-Earth archetype GJ 1214b, but previous observations did not have sufficient precision to distinguish between two interpretations for the atmosphere. The planet's atmosphere could be dominated by relatively heavy molecules, such as water (e.g., a 100% water vapor composition), or it could contain high-altitude clouds that obscure its lower layers. Here we report a measurement of the transmission spectrum of GJ 1214b at near-infrared wavelengths that definitively resolves this ambiguity. These data, obtained with the Hubble Space Telescope, are sufficiently precise to detect absorption features from a high mean molecular mass atmosphere. The observed spectrum, however, is featureless. We rule out cloud-free atmospheric models with water-, methane-, carbon monoxide-, nitrogen-, or carbon dioxide-dominated compositions at greater than 5\(\sigma\) confidence. The planet's atmosphere must contain clouds to be consistent with the data.