Repurposing of nickeliferous pyrrhotite from mine tailings as magnetic adsorbent for the recovery of gold from chloride solution

Acid mine/rock drainage (AMD/ARD), effluents with low pH and high concentrations of hazardous and toxic elements generated when sulfide-rich wastes are exposed to the environment, is considered as a serious environmental problem encountered by the mining and mineral processing industries around the world. Remediation options like neutralization, adsorption, ion exchange, membrane technology, biological mediation, and electrochemical approach have been developed to reduce the negative environmental impacts of AMD on ecological systems and human health. However, these techniques require the continuous supply of chemicals and energy, expensive maintenance and labor cost, and long-term monitoring of affected ecosystems until AMD generation stops. Unfortunately, the formation of AMD could persist for hundreds or even thousands of years, so these approaches are both costly and unsustainable. Recently, two alternative strategies for the management of AMD and mine tailings are gaining much attention: (1) prevention techniques, and (2) mine waste recycling. In this review, recent advances in AMD prevention techniques like oxygen barriers, utilization of bactericides, co-disposal and blending, and passivation of sulfide minerals are discussed. In addition, recycling of mine tailings as construction and geopolymer materials to reduce the amounts of wastes for disposal are introduced.

The use of magnetic materials in solid phase extraction has received considerable attention in recent years taking into account many advantages arising from the inherent characteristics of magnetic particles. Magnetic solid phase extraction (MSPE) methodology overcomes problems such as column packing and phase separation, which can be easily performed by applying an external magnetic field. The use of magnetic particles in automatic systems is growing over the last few years making the on-line operation of MSPE a promising technique in the frame of green chemistry. This article aims to provide all recent progress in the research of novel magnetic materials as sorbents for metal preconcentration and determination coupled with different detection systems as well as their implementation in sequential injection and microfluidic systems. In addition, a description of preparation, characterization as well as applications of various types of magnetic materials, either with organic or inorganic coating of the magnetic core, is presented. Concluding remarks and future trends are also commented.