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      CO self-shielding as the origin of oxygen isotope anomalies in the early solar nebula

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      Nature
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          Layered Accretion in T Tauri Disks

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            The oxygen isotope record in Murchison and other carbonaceous chondrites

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              Strange and Unconventional Isotope Effects in Ozone Formation

              The puzzling mass-independent isotopic enrichment in ozone formation contrasts markedly with the more recently observed large unconventional mass-dependent ratios of the individual ozone formation rate constants in certain systems. An RRKM (Rice, Ramsperger, Kassel, Marcus)-based theory is used to treat both effects. Restrictions of symmetry on how energy is shared among the rotational/vibrational states of the ozone isotopomer, together with an analysis of the competition between the transition states of its two exit channels, permit the calculation of isotope effects consistent with a wide array of experimental results.
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                Author and article information

                Journal
                Nature
                Nature
                Springer Nature
                0028-0836
                1476-4679
                May 19 2005
                May 19 2005
                : 435
                : 7040
                : 317-320
                Article
                10.1038/nature03557
                0311ba26-aa36-42aa-a35d-7ff81724bc76
                © 2005
                History

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