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      Discovery of methyl silane and confirmation of silyl cyanide in IRC +10216⋆

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          Abstract

          We report the discovery in space of methyl silane, CH 3SiH 3, from observations of ten rotational transitions between 80 and 350 GHz ( J u from 4 to 16) with the IRAM 30 m radio telescope. The molecule was observed in the envelope of the C-star IRC +10216. The observed profiles and our models for the expected emission of methyl silane suggest that the it is formed in the inner zones of the circumstellar envelope, 1–40 R *, with an abundance of (0.5–1) × 10 −8 relative to H 2. We also observed several rotational transitions of silyl cyanide (SiH 3CN), confirming its presence in IRC +10216 in particular, and in space in general. Our models indicate that silyl cyanide is also formed in the inner regions of the envelope, around 20 R *, with an abundance relative to H 2 of 6×10 −10. The possible formation mechanisms of both species are discussed. We also searched for related chemical species but only upper limits could be obtained.

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          The Cologne Database for Molecular Spectroscopy, CDMS: a useful tool for astronomers and spectroscopists

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            SUBMILLIMETER, MILLIMETER, AND MICROWAVE SPECTRAL LINE CATALOG

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              Atmospheric transmission at microwaves (ATM): an improved model for millimeter/submillimeter applications

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                Author and article information

                Journal
                100971304
                22542
                Astron Astrophys
                Astron Astrophys
                Astronomy and astrophysics
                0004-6361
                3 November 2017
                9 October 2017
                October 2017
                13 November 2017
                : 606
                : L5
                Affiliations
                [1 ]Group of Molecular Astrophysics, ICMM, CSIC, C/ Sor Juana Inés de La Cruz 3, 28049 Madrid, Spain
                [2 ]Institut de Radioastronomie Millimétrique, 300 rue de la Piscine, 38406 St-Martin d’Hères, France
                [3 ]Université Grenoble Alpes, CNRS, IPAG, 38000 Grenoble, France
                [4 ]Instituto de Radioastronomía Milimétrica, Av. Divina Pastora 7, Local 20, 18012 Granada, Spain
                [5 ]Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138, and School of Engineering & Applied Sciences, Harvard University, Cambridge, MA 02138, USA
                [6 ]Grupo de Espectroscopía Molecular (GEM), Edificio Quifima, Área de Química-Física, Laboratorios de Espectroscopía y Bioespectroscopía, Parque Científico UVa, Unidad Asociada CSIC, Universidad de Valladolid, 47011 Valladolid, Spain
                Author notes
                [⋆]

                This work was based on observations carried out with the IRAM 30-m telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain).

                Article
                PMC5683346 PMC5683346 5683346 ems74779
                10.1051/0004-6361/201731672
                5683346
                29142328
                fcd66e86-61a3-4c7b-b436-83fd5dcba0a1
                History
                Categories
                Article

                stars: individual: IRC+10216,stars: carbon,astrochemistry,stars: AGB and post-AGB

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